X-ray and Synchrotron FTIR Studies of Partially Decomposed Magnesium Borohydride

نویسندگان

چکیده

Magnesium borohydride (Mg(BH4)2) is an attractive compound for solid-state hydrogen storage due to its lucratively high densities and theoretically low operational temperature. Hydrogen release from Mg(BH4)2 occurs through several steps. The reaction intermediates formed at these steps have been extensively studied a decade. In this work, we apply spectroscopic methods that rarely used in such studies provide alternative insights into the nature of intermediates. commercially obtained sample was decomposed argon flow during thermogravimetric analysis combined with differential scanning calorimetry (TGA-DSC) differentiate between H2-desorption products were analyzed by powder X-ray diffraction (PXRD), near edge soft absorption spectroscopy boron K-edge (NEXAFS), synchrotron infrared (IR) mid- far-IR ranges (SR-FTIR). Up 12 wt% H2 desorption observed gravimetric measurements. PXRD showed no crystalline decomposition when heated 260–280 °C, formation MgH2 above 300 Mg 320 °C. qualitative NEXAFS data presence lower oxidation states than (BH4)−. also indicated amorphous 340 This study provides additional Mg(BH4)2.

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ژورنال

عنوان ژورنال: Energies

سال: 2022

ISSN: ['1996-1073']

DOI: https://doi.org/10.3390/en15217998